Details

Autor(en) / Beteiligte

• Chen, Xin
• Qi, Dongdong
• Liu, Chao
• Wang, Hailong
• Xie, Zheng
• Chen, Tse-Wei
• Chen, Shen-Ming
• Tseng, Tien-Wen
• Jiang, Jianzhuang

Titel

Elucidating π-π interaction-induced extension effect in sandwich phthalocyaninato compounds

Ist Teil von

• RSC advances, 2020-01, Vol.1 (1), p.317-322

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2020

Quelle

EZB Electronic Journals Library

Beschreibungen/Notizen

• Electrochemical and theoretical investigations over triple-quadruple-, quintuple-, and sextuple-decker sandwich-type compounds {[(Pc*)Sm][(Pc*)Cd n (Pc*) n ][Sm(Pc*)]} ( n = 0-3) elucidate successive π-π interaction-linked extension in the perpendicular direction of the phthalocyanine plane along with increasing the stacked tetrapyrrole number, significantly improving the nonlinear optical properties including effective imaginary third order molecular hyperpolarizability and optical limiting threshold. π-π interaction-linked extension in the perpendicular direction to the monomers and corresponding effect on nonlinear optic properties have been clearly disclosed over the multiple-decker sandwich-type phthalocyaninato metal compounds.