Details

Autor(en) / Beteiligte

• Li, Siwen
• Fan, Xiayue
• Liu, Xiaorui
• Zhao, Zequan
• Xu, Wen
• Wu, Zhanyao
• Feng, Zhonghou
• Zhong, Cheng
• Hu, Wenbin

Titel

Potassium Polyacrylate-Based Gel Polymer Electrolyte for Practical Zn–Ni Batteries

Ist Teil von

• ACS applied materials & interfaces, 2022-05, Vol.14 (20), p.22847-22857

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2022

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Because of their high theoretical value of volumetric energy density, excellent rate performance, and high level of safety, zinc–nickel batteries (ZNBs) show potential applications for uninterrupted power supply (UPS) systems. However, despite all the advantages of ZNBs, the commercial application of ZNBs has been prevented by their short lifetime caused by the shape change, the corrosion, and the dendrite formation of the Zn anode. In this work, we proposed a flexible and durable potassium polyacrylate (PAAK)–KOH gel polymer electrolyte (GPE) prepared in a very simple way to solve the above problems of the Zn anode. The obtained highly porous gel electrolyte showed higher water retention, satisfying ionic conductivity (0.918 S cm–1), and a broad electrochemical stable voltage window. By providing a stable and homogeneous electrode/electrolyte interface for the Zn anode, the gel electrolyte can inhibit the uneven deposition and dendrite formation. As a result, the gel electrolyte greatly prolonged the cycling life to 776 h. In addition, because of the considerably batter corrosion resistance of the Zn anode in the PAAK–KOH GPE, the ZNB with gel electrolyte also exhibited a superior shelf life of more than 431 h and a superior cycling performance under float charge for more than 400 h at 60 °C. This work demonstrates that the gel electrolyte with a simple preparation method is suitable for large-scale practical production and can be successfully used in Zn–Ni batteries as an electrolyte exhibiting excellent performance.