Details

Autor(en) / Beteiligte

• Ikuhara, Yumi H
• Gao, Xiang
• Kawahara, Kazuaki
• Fisher, Craig A. J
• Kuwabara, Akihide
• Ishikawa, Ryo
• Moriwake, Hiroki
• Ikuhara, Yuichi

Titel

Atomic-Level Changes during Electrochemical Cycling of Oriented LiMn2O4 Cathodic Thin Films

Ist Teil von

• ACS applied materials & interfaces, 2022-02, Vol.14 (5), p.6507-6517

Ort / Verlag

American Chemical Society

Erscheinungsjahr

2022

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Spinel LiMn2O4 is an attractive lithium-ion battery cathode material that undergoes a complex series of structural changes during electrochemical cycling that lead to rapid capacity fading, compromising its long-term performance. To gain insights into this behavior, in this report we analyze changes in epitaxial LiMn2O4 thin films during the first few charge–discharge cycles with atomic resolution and correlate them with changes in the electrochemical properties. Impedance spectroscopy and scanning transmission electron microscopy are used to show that defect-rich LiMn2O4 surfaces contribute greatly to the increased resistivity of the battery after only a single charge. Sequences of {111} stacking faults within the films were also observed upon charging, increasing in number with further cycling. The atomic structures of these stacking faults are reported for the first time, showing that Li deintercalation is accompanied by local oxygen loss and relaxation of Mn atoms onto previously unoccupied sites. The stacking faults have a more compressed structure than the spinel matrix and impede Li-ion migration, which explains the observed increase in thin-film resistivity as the number of cycles increases. These results are used to identify key factors contributing to conductivity degradation and capacity fading in LiMn2O4 cathodes, highlighting the need to develop techniques that minimize defect formation in spinel cathodes to improve cycle performance.