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Pomegranate-like structured Nb2O5/Carbon@N-doped carbon composites as ultrastable anode for advanced sodium/potassium-ion batteries
Ist Teil von
Journal of colloid and interface science, 2022-05, Vol.613, p.84-93
Ort / Verlag
Elsevier Inc
Erscheinungsjahr
2022
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
[Display omitted]
The distinctive pomegranate-like Nb2O5/Carbon@N-doped carbon (Nb2O5/C@NC) composites are fabricated using hydrothermal method integrated with nitrogen doped carbon coating procedure. For the SIBs anode, the Nb2O5/C@NC composites present superior rate character and sustainable capacity (117 mAh g−1 upon 1000 cycles at 5 A g−1). The in-situ X-ray diffraction (XRD) is utilized to research its sodium storage mechanism. Furthermore, for PIBs, the Nb2O5/C@NC composites present sustainable capacity (81 mAh g−1 upon 1000 cycles at 1 A g−1). The outstanding performance of Nb2O5/C@NC composites is ascribed to its unique architecture, in which Nb2O5 nanocrystals embedded in porous carbon can restrain agglomeration of Nb2O5 nanocrystals, enhance electron/ion diffusion kinetics, and ensure electrolyte accessibility, and moreover, NC shell layer can provide effective active sites and further increase ions/electrons transfer.