Details

Autor(en) / Beteiligte

• Meng, Yu‐Feng
• Zhu, Yin‐Bo
• Zhou, Li‐Chuan
• Meng, Xiang‐Sen
• Yang, Yu‐Lu
• Zhao, Ran
• Xia, Jun
• Yang, Bo
• Lu, Yu‐Jie
• Wu, Heng‐An
• Mao, Li‐Bo
• Yu, Shu‐Hong

Titel

Artificial Nacre with High Toughness Amplification Factor: Residual Stress‐Engineering Sparks Enhanced Extrinsic Toughening Mechanisms

Ist Teil von

• Advanced materials (Weinheim), 2022-03, Vol.34 (9), p.e2108267-n/a

Ort / Verlag

Germany: Wiley Subscription Services, Inc

Erscheinungsjahr

2022

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The high fracture toughness of mollusk nacre is predominantly attributed to the structure‐associated extrinsic mechanisms such as platelet sliding and crack deflection. While the nacre‐mimetic structures are widely adopted in artificial ceramics, the extrinsic mechanisms are often weakened by the relatively low tensile strength of the platelets with a large aspect ratio, which makes the fracture toughness of these materials much lower than expected. Here, it is demonstrated that the fracture toughness of artificial nacre materials with high inorganic contents can be improved by residual stress‐induced platelet strengthening, which can catalyze more effective extrinsic toughening mechanisms that are specific to the nacre‐mimetic structures. Thereby, while the absolute fracture toughness of the materials is not comparable with advanced ceramic‐based composites, the toughness amplification factor of the material reaches 16.1 ± 1.1, outperforming the state‐of‐the‐art biomimetic ceramics. The results reveal that, with the merit of nacre‐mimetic structural designs, the overall fracture toughness of the artificial nacre can be improved by the platelet strengthening through extrinsic toughening mechanisms, although the intrinsic fracture toughness may decrease at platelet level due to the strengthening. It is anticipated that advanced structural ceramics with exceeding performance can be fabricated through these unconventional strategies. This work illustrates an anti‐intuitive strategy that, with the merit of biomimetic designs, residual stress that is conventionally harmful to ceramics can inversely help improve the fracture toughness of biomimetic ceramics through nanoscale residual stress‐induced platelet strengthening. This provides new insights into the design principles of nacre‐like materials at the bottom level.