Details

Autor(en) / Beteiligte

• Bose, Shubhankar Kumar
• Mao, Lujia
• Kuehn, Laura
• Radius, Udo
• Nekvinda, Jan
• Santos, Webster L
• Westcott, Stephen A
• Steel, Patrick G
• Marder, Todd B

Titel

First-Row d‑Block Element-Catalyzed Carbon–Boron Bond Formation and Related Processes

Ist Teil von

• Chemical reviews, 2021-11, Vol.121 (21), p.13238-13341

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2021

Link zum Volltext

Quelle

MEDLINE

Beschreibungen/Notizen

• Organoboron reagents represent a unique class of compounds because of their utility in modern synthetic organic chemistry, often affording unprecedented reactivity. The transformation of the carbon–boron bond into a carbon–X (X = C, N, and O) bond in a stereocontrolled fashion has become invaluable in medicinal chemistry, agrochemistry, and natural products chemistry as well as materials science. Over the past decade, first-row d-block transition metals have become increasingly widely used as catalysts for the formation of a carbon–boron bond, a transformation traditionally catalyzed by expensive precious metals. This recent focus on alternative transition metals has enabled growth in fundamental methods in organoboron chemistry. This review surveys the current state-of-the-art in the use of first-row d-block element-based catalysts for the formation of carbon–boron bonds.