Details

Autor(en) / Beteiligte

• Ma, Xinyuan
• Guillet, Sébastien G
• Liu, Yaxu
• Cazin, Catherine S. J
• Nolan, Steven P

Titel

Simple synthesis of [Ru(CO)(NHC)(-cymene)] complexes and their use in transfer hydrogenation catalysis

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2021-09, Vol.5 (37), p.1312-1319

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A novel, efficient and facile protocol for the synthesis of a series of [Ru(NHC)(CO 3 )( p -cymene)] complexes is reported. This family of Ru-NHC complexes was obtained from imidazol(in)ium tetrafluoroborate or imidazolium hydrogen carbonate salts in moderate to excellent yields, employing sustainable weak base. The ruthenium complexes were successfully utilized in the transfer hydrogenation of ketones as highly active multifunctional catalysts. A novel, efficient and facile protocol for the synthesis of a series of [Ru(NHC)(CO 3 )( p -cymene)] complexes is reported.