Details

Autor(en) / Beteiligte

• do Pim, Walace D
• Silva, Ingrid F
• da Silva Júnior, Eufrânio N
• Stumpf, Humberto O
• Oliveira, Willian X. C
• Pedroso, Emerson F
• Pinheiro, Carlos B
• Journaux, Yves
• Fantuzzi, Felipe
• Krummenacher, Ivo
• Braunschweig, Holger
• Engels, Bernd
• Cano, Joan
• Julve, Miguel
• Pereira, Cynthia L. M

Titel

Unexpected formation of a dodecanuclear {CoCu} nanowheel under ambient conditions: magneto-structural correlations

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2021-09, Vol.5 (36), p.1243-12434

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• We report the unique heterobimetallic dodecanuclear oxamate-based {Co II 6 Cu II 6 } nanowheel obtained using an environmentally friendly synthetic protocol. The effective Hamiltonian methodology employed herein allows the rationalisation of magnetic isotropic or anisotropic metal clusters, being a significant advance for future studies of exciting properties only observed at low and ultralow temperatures. An unexpected heterobimetallic ring {Co II 6 Cu II 6 } was synthesised by slow diffusion in water under ambient conditions and its dc magnetic properties were analysed through an effective Hamiltonian in the light of DFT type calculations.