Details

Autor(en) / Beteiligte

• Chen, Yang
• Zhang, Dongdong
• Zhang, Yuewei
• Zeng, Xuan
• Huang, Tianyu
• Liu, Ziyang
• Li, Guomeng
• Duan, Lian

Titel

Approaching Nearly 40% External Quantum Efficiency in Organic Light Emitting Diodes Utilizing a Green Thermally Activated Delayed Fluorescence Emitter with an Extended Linear Donor–Acceptor–Donor Structure

Ist Teil von

• Advanced materials (Weinheim), 2021-11, Vol.33 (44), p.e2103293-n/a

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2021

Quelle

Wiley Online Library - AutoHoldings Journals

Beschreibungen/Notizen

• Thermally activated delayed fluorescence (TADF) emitters featuring preferential horizontal emitting dipole orientation (EDO) are in urgent demand for enhanced optical outcoupling efficiency in organic light‐emitting diodes (OLEDs). However, simultaneously manipulating EDO and optoelectronic properties remains a formidable challenge. Here, an extended linear D–A–D structure with both enlarged donor (D) and acceptor (A) π‐systems is established, not only elaborately manipulating parallel horizontal molecular orientation and EDO along its long axis by multi‐driving‐forces for a high horizontal dipole ratio (Θ//), but also delocalizing distribution of frontier energy levels for optimized electronic properties. The proof‐of‐the‐concept emitter simultaneously affords a high Θ// of 92%, a high photoluminescence quantum yield of 95%, and a fast reverse intersystem crossing rate of 1.16 × 106 s‐1. The corresponding OLED achieves a champion maximum external quantum efficiency of 39.1% among all green TADF devices without any external light‐extraction techniques, together with a maximum power efficiency of 112.0 lm W‐1 and alleviated efficiency roll‐off. These findings may inspire even better full‐color TADF emitters that push the device efficiency toward the theoretical limits. A green thermally activated delayed fluorescence (TADF) emitter with an extended π‐system of linear donor (D)–acceptor (A)–donor (D) structure is established to simultaneously obtain a horizontal emitting dipole orientation ratio of 92%, a reverse intersystem crossing rate of 1.16 × 106 s–1 and a photoluminescence quantum yield of 95%, together affording a champion maximum external quantum efficiency of 39.1%.