Details

Autor(en) / Beteiligte

• Chen, Zi-Hao
• Wang, Yao
• Xu, Rui-Xue
• Yan, YiJing

Titel

Correlated vibration–solvent effects on the non-Condon exciton spectroscopy

Ist Teil von

• The Journal of chemical physics, 2021-06, Vol.154 (24), p.244105-244105

Ort / Verlag

Melville: American Institute of Physics

Erscheinungsjahr

2021

Link zum Volltext

Quelle

AIP Journals (American Institute of Physics)

Beschreibungen/Notizen

• Excitation energy transfer is crucially involved in a variety of systems. During the process, the non-Condon vibronic coupling and the surrounding solvent interaction may synergetically play important roles. In this work, we study the correlated vibration–solvent influences on the non-Condon exciton spectroscopy. Statistical analysis is elaborated for the overall vibration-plus-solvent environmental effects. Analytic solutions are derived for the linear absorption of monomer systems. General simulations are accurately carried out via the dissipaton-equation-of-motion approach. The resulted spectra in either the linear absorption or strong field regime clearly demonstrate the coherence enhancement due to the synergetic vibration–solvent correlation.