Details

Autor(en) / Beteiligte

• McMullen, Jacob S
• Edwards, Alison J
• Hicks, Jamie

Titel

C-H and C-F coordination of arenes in neutral alkaline earth metal complexes

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2021-06, Vol.5 (25), p.8685-8689

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A series of neutral magnesium and calcium complexes bearing an extremely bulky diamido ligand have been synthesised and crystallographically characterised. A number of these complexes feature rare group 2 metal aromatic interactions, such as the η 6 -coordination of benzene and 'agostic-like' C-H coordination, the latter previously unseen in neutral Mg and Ca complexes. A series of neutral magnesium and calcium complexes that display various novel group 2 arene interaction have been synthesised and structurally characterised.