Details

Autor(en) / Beteiligte

• Dong, Maolin
• Wu, Chen
• Chen, Lidong
• Zhou, Xuelian
• Yang, Weisheng
• Xiao, Huining
• Ji, Xingxiang
• Dai, Hongqi
• Hu, Chaoquan
• Bian, Huiyang

Titel

Benzenesulfonic acid-based hydrotropic system for achieving lignocellulose separation and utilization under mild conditions

Ist Teil von

• Bioresource technology, 2021-10, Vol.337, p.125379-125379, Article 125379

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• •Benzenesulfonic acid was used as a green hydrotrope for lignocellulose fractionation.•Approximately 80% lignin were removed using lower acid concentration (≤70 wt%).•The hydrolyzed fiber could be fibrillated into LCNF or converted into sugars.•The lignin particles size could be easily adjusted by the initial acid concentration. Developing low-cost and sustainable fractionation technology is the key to achieve the maximal utilization of lignocellulosic biomass. This study reported benzenesulfonic acid (BA) as a green hydrotrope for efficient lignocellulose conversion into two fractions at atmospheric pressure: (1) a primarily cellulosic solid residue that can be utilized to produce high-value building blocks (lignocellulosic nanomaterials or sugars), and (2) the collected spent acid liquor that can be diluted with anti-solvent to easily obtain lignin nanoparticles. BA hydrotropic method exhibited greater reaction selectivity to solubilize lignin, where approximately 80% lignin were removed at only 80 °C in 20 min. The lower lignin content substrates resulted in relatively higher enzymatic hydrolysis efficiency of 80% and less entangled lignocellulosic nanofibrils (LCNF). Furthermore, the separated lignin particles size can be easily adjusted by the initial acid concentration. Overall, this work presented a promising and simple technology in achieving lignocellulose separation and utilization under mild conditions.