Details

Autor(en) / Beteiligte

• Meng, Ze-Yin
• Feng, Cheng-Tao
• Zhang, Ling
• Yang, Qing
• Chen, De-Xiang
• Xu, Kun

Titel

Regioselective C–H Phosphorothiolation of (Hetero)arenes Enabled by the Synergy of Electrooxidation and Ultrasonic Irradiation

Ist Teil von

• Organic letters, 2021-06, Vol.23 (11), p.4214-4218

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• An electrochemically regioselective C–H phosphorothiolation of (hetero)­arenes with thiocyanate as the S source under ultrasonic irradiation has been developed. The synergistic cooperation of electrooxidation and ultrasonication markedly accelerated the C–H phosphorothiolation reaction. This mechanistically different method is distinguished by its wide substrate scope and transition-metal-free and external-oxidant-free conditions, thus complementing the existing metal-catalyzed or peroxide-mediated protocols for the green synthesis of S-(hetero)­aryl phosphorothioates.