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Symmetric and Asymmetric Push–Pull Conjugates: Significance of Pull Group Strength on Charge Transfer and Separation
Ist Teil von
The journal of physical chemistry. B, 2021-04, Vol.125 (16), p.4067-4075
Ort / Verlag
United States: American Chemical Society
Erscheinungsjahr
2021
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The effect of acceptor strength on excited-state charge transfer (CT) and charge separation (CS) in central phenothiazine (PTZ)-derived symmetric 1 (PTZ-(TCBD-TPA)2) and asymmetric 2 (PTZ-(TCBD/DCNQ-TPA)2) push–pull conjugates, in which triphenylamine (TPA) acts as end capping and 1,1,4,4–tetracyanobuta–1,3–diene (TCBD) and cyclohexa–2,5–diene–1,4–ylidene–expanded TCBD (DCNQ) act as electron acceptor units, is reported. Due to strong push–pull effects, intramolecular CT was observed in the ground state, extending the absorption into the near-infrared region. Electrochemical, spectroelectrochemical, and computational studies coupled with energy-level calculations predicted both 1 and 2 to be efficient candidates for ultrafast CT. Subsequent femtosecond transient absorption studies along with global target analysis, performed in both polar and nonpolar solvents, confirmed such processes in which the CS was efficient in asymmetric 2, having both TCBD and DCNQ acceptors in polar benzonitrile, while in toluene, only CT was witnessed. This work highlights the significance of the number and strength of electron acceptor entities and the role of solvent polarity in multimodular push–pull systems to achieve ultrafast CS.