Details

Autor(en) / Beteiligte

• Naganawa, Yuki
• Sakamoto, Kei
• Nakajima, Yumiko

Titel

A General and Selective Synthesis of Methylmonochlorosilanes from Di-, Tri-, and Tetrachlorosilanes

Ist Teil von

• Organic letters, 2021-01, Vol.23 (2), p.601-606

Ort / Verlag

United States

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Direct catalytic transformation of chlorosilanes into organosilicon compounds remains challenging due to difficulty in cleaving the strong Si-Cl bond(s). We herein report the palladium-catalyzed cross-coupling reaction of chlorosilanes with organoaluminum reagents. A combination of [Pd(C H )Cl] and DavePhos ligand catalyzed the selective methylation of various dichlorosilanes , trichlorosilanes , and tetrachlorosilane to give the corresponding monochlorosilanes.