Details

Autor(en) / Beteiligte

• Sathish Kumar, B
• Pati, Narendra N
• Jose, K V Jovan
• Panda, Pradeepta K

Titel

Synthetic access to calix[3]pyrroles via meso-expansion: hosts with diverse guest chemistry

Ist Teil von

• Chemical communications (Cambridge, England), 2020-05, Vol.56 (42), p.5637-5640

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2020

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Calix[3]pyrroles were synthesized for the first time. These macrocycles display versatile guest binding ability based on the bridges connecting the two α-positions of the tripyrrane moiety e.g. with an ethene bridge they showed colorimetric sensing of fluoride and cyanide ions, whereas with a phenylene spacer they exhibited fluorometric sensing of fluoride ions only, and the macrocycle with an ethylene unit acted as a host towards the water molecule with unique penta-coordinated oxygen in the solid state.