Details

Autor(en) / Beteiligte

• Chen, Yue
• Qiu, Linlin
• Ma, Xiangyu
• Dong, Lika
• Jin, Zhengfei
• Xia, Guangbo
• Du, Pingfan
• Xiong, Jie

Titel

Electrospun cellulose polymer nanofiber membrane with flame resistance properties for lithium-ion batteries

Ist Teil von

• Carbohydrate polymers, 2020-04, Vol.234, p.115907-115907, Article 115907

Ort / Verlag

England: Elsevier Ltd

Erscheinungsjahr

2020

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• [Display omitted] •PVDF/TPP/CA composite membranes are prepared by one-step electrospinning.•PVDF/TPP/CA composite membranes show flame resistance properties.•PVDF/TPP/CA membranes have improved electrolyte wettability and thermal stability.•PVDF/TPP/CA-based batteries have high capacities and better rate performances. Current developments of lithium-ion batteries (LIBs) are mainly focused on improving security and cycle performance. Herein, a novel polyvinylidene fluoride (PVDF)/triphenyl phosphate (TPP)/cellulose acetate (CA) nanofiber membrane was fabricated by one-step electrospinning and used as separator in lithium-ion batteries. Compared to traditional polyethylene membrane, the obtained composite showed higher porosity, elevated thermal stability, superior electrolyte wettability, and improved flame resistance. In addition, batteries assembled with PVDF/TPP/CA membrane exhibited excellent electrochemical properties and cycle stability. The enhanced performances were attributed to the porous structure and presence of CA and TPP. Overall, the proposed hybrid organic cellulose-based composite polymer membranes look promising as separators for advanced LIBs.