Chemical communications (Cambridge, England), 2020-02, Vol.56 (11), p.1693-1696
2020
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Details
- Autor(en) / Beteiligte
- Titel
- Copper-catalyzed asymmetric silyl addition to alkenyl-substituted N-heteroarenes
- Ist Teil von
- Chemical communications (Cambridge, England), 2020-02, Vol.56 (11), p.1693-1696
- Ort / Verlag
- England: Royal Society of Chemistry
- Erscheinungsjahr
- 2020
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Asymmetric conjugate addition of PhMe2SiBPin to a wide range of N-heteroaryl alkenes proceeded in the presence of a copper catalyst coordinated with an easily accessible chiral phosphoramidite ligand to afford useful β-silyl N-heteroarenes in high yields (up to 96%) and excellent enantioselectivities (up to 97% ee).
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1359-7345eISSN: 1364-548XDOI: 10.1039/c9cc08910aTitel-ID: cdi_proquest_miscellaneous_2338991345
- Format
- –
- Schlagworte
- Alkenes, Asymmetry, Copper, Crystal structure, Crystallography, NMR, Nuclear magnetic resonance