Details

Autor(en) / Beteiligte

• Shen, Yao-Bin
• Li, Long-Fei
• Xiao, Ming-Yan
• Yang, Jian-Ming
• Liu, Qing
• Xiao, Jian

Titel

Redox-Neutral Cascade Dearomatization of Indoles via Hydride Transfer: Divergent Synthesis of Tetrahydroquinoline-Fused Spiroindolenines

Ist Teil von

• Journal of organic chemistry, 2019-11, Vol.84 (21), p.13935-13947

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2019

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The redox-neutral cascade dearomatization of indoles with o-aminobenzaldehydes has been realized via the hydride transfer strategy, achieving the condition- and substrate-controlled divergent synthesis of tetrahydroquinoline-fused spiroindolenines. The integration of hydride transfer-involved C­(sp3)–H functionalization with dearomatization provides a promising platform for the construction of structurally diverse molecules.