Details

Autor(en) / Beteiligte

• Wu, Licheng
• Li, Feilong
• Rao, Yutao
• Wen, Bin
• Xu, Ling
• Zhou, Mingbo
• Tanaka, Takayuki
• Osuka, Atsuhiro
• Song, Jianxin

Titel

Synthesis, Structures, and Near‐IR Absorption of Heterole‐Fused Earring Porphyrins

Ist Teil von

• Angewandte Chemie International Edition, 2019-06, Vol.58 (24), p.8124-8128

Auflage

International ed. in English

Ort / Verlag

Germany: Wiley Subscription Services, Inc

Erscheinungsjahr

2019

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A reaction sequence of regioselective peripheral bromination, Suzuki–Miyaura coupling with 2‐borylated thiophene or pyrrole, and oxidative ring‐closure with FeCl3 allowed the synthesis of heterole‐fused earring porphyrins 4Pd and 9Pd from the parent earring porphyrin 1. Differently pyrrole‐fused porphyrins 5H and 6H and their PdII complexes 5Pd and 6Pd were also synthesized. The structures of 4Pd, 5H, 6Pd, and 8Pd have been revealed by X‐ray analysis to be slightly twisted owing to constraints imposed by heterole‐fused structures. 5Pd exhibits an intensified band at 1505 nm, while 4Pd and 9Pd display small but remarkably red‐shifted absorption bands reaching around 2200 nm. Fancy earrings: A series of substituted and fused earring porphyrins were regioselectively synthesized from the brominated earring porphyrin 2. The structures of 4Pd, 5H, and 8Pd are slightly twisted owing to constraints imposed by doubly heterole‐fused structures. 5Pd exhibits an intensified band at 1505 nm, while 4Pd and 9Pd display small but remarkably red‐shifted absorption bands reaching around 2200 nm.