Details

Autor(en) / Beteiligte

• Masoomi, Mohammad Yaser
• Morsali, Ali
• Dhakshinamoorthy, Amarajothi
• Garcia, Hermenegildo

Titel

Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design

Ist Teil von

• Angewandte Chemie (International ed.), 2019-10, Vol.58 (43), p.15188-15205

Auflage

International ed. in English

Ort / Verlag

Germany: Wiley Subscription Services, Inc

Erscheinungsjahr

2019

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Mixed‐metal metal–organic frameworks (MM‐MOFs) can be considered to be those MOFs having two different metals anywhere in the structure. Herein we summarize the various strategies for the preparation of MM‐MOFs and some of their applications in adsorption, gas separation, and catalysis. It is shown that compared to homometallic MOFs, MM‐MOFs bring about the opportunity to take advantage of the complexity and the synergism derived from the presence of different metal ions in the structure of MOFs. This is reflected in a superior performance and even stability of MM‐MOFs respect to related single‐metal MOFs. Emphasis is made on the use of MM‐MOFs as catalysts for tandem reactions. Mix and miss‐match: This Minireview summarizes the recent developments on the synthesis of mixed‐metal metal–organic frameworks (MM‐MOFs). Such multivariate MOFs represent a higher degree of complexity than homometallic MOFs, frequently showing advantages over simple MOFs with respect to their properties and applications, particularly in heterogeneous catalysis.