Details

Autor(en) / Beteiligte

• Ou, Jinhua
• Xiang, Juan
• Liu, Jinxuan
• Sun, Licheng

Titel

Surface-Supported Metal–Organic Framework Thin-Film-Derived Transparent CoS1.097@N-Doped Carbon Film as an Efficient Counter Electrode for Bifacial Dye-Sensitized Solar Cells

Ist Teil von

• ACS applied materials & interfaces, 2019-04, Vol.11 (16), p.14862-14870

Ort / Verlag

American Chemical Society

Erscheinungsjahr

2019

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• An effective design for counter electrode (CE) catalytic materials with superior catalytic activity, excellent stability, low cost, and a facile fabrication process is urgently needed for industrialization of dye-sensitized solar cells (DSSCs). Herein, we report a facile in situ method to fabricate transparent CoS1.097 anchored on an N-doped carbon film electrode through sulfurization of a cobalt–metalloporphyrin metal–organic framework thin film on fluorine-doped tin oxide glass. The transparent film as counter electrode in bifacial DSSCs exhibited higher power conversion efficiency (9.11% and 6.64%), respectively, from front and rear irradiation than that of Pt (8.04% and 5.87%). The uniformly dispersed CoS1.097 nanoparticles on an N-doped carbon film provide a large catalytic active area and facilitate the electron transfer, which leads to the excellent catalytic ability of the CoS1.097@N-doped carbon film. In addition, the in situ preparation of the uniform film with a nanosheet structure offers high electrical conductivity and unobstructed access for the diffusion of triiodide to available electroactive sites, resulting in excellent device performance with superior long-term stability over 1000 h under natural conditions.