Details

Autor(en) / Beteiligte

• Martínez‐Agramunt, Victor
• Eder, Tobias
• Darmandeh, Heidar
• Guisado‐Barrios, Gregorio
• Peris, Eduardo

Titel

A Size‐Flexible Organometallic Box for the Encapsulation of Fullerenes

Ist Teil von

• Angewandte Chemie International Edition, 2019-04, Vol.58 (17), p.5682-5686

Auflage

International ed. in English

Ort / Verlag

Germany: Wiley Subscription Services, Inc

Erscheinungsjahr

2019

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A palladium‐cornered molecular square with four pyrene‐bis(imidazolylidene) bridging ligands is reported. This metallo‐polygon can encapsulate C60 and C70. The X‐ray diffraction structures of the empty cage as well as the cages complexed with both fullerenes are described. The fullerene encapsulation produces perturbations in the structural parameters of the metallo‐square, showing that it can adjust the shape of its cavity to the size of each fullerene. A palladium‐cornered cubic box with four pyrene‐bis(imidazolylidene) bridging ligands encapsulates C60 and C70 fullerenes. Fullerene encapsulation induces perturbations in the structural parameters of the metallo‐square, showing that it can adjust the shape of its cavity to the size of each fullerene.