Details

Autor(en) / Beteiligte

• Zhang, Lingling
• Zhang, Guoting
• Wang, Pan
• Li, Yongli
• Lei, Aiwen

Titel

Electrochemical Oxidation with Lewis-Acid Catalysis Leads to Trifluoromethylative Difunctionalization of Alkenes Using CF3SO2Na

Ist Teil von

• Organic letters, 2018-12, Vol.20 (23), p.7396-7399

Ort / Verlag

American Chemical Society

Erscheinungsjahr

2018

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The directly external oxidant-free oxytrifluoromethylation and aminotrifluoromethylation of alkenes have been developed through the constant current electrolysis synergizing with a Lewis-acid catalysis protocol. By using sodium trifluoromethanesulfinate as the trifluoromethyl source, the method enabled difunctionalization of C–C double bonds of a wide range of styrene derivatives.