Details

Autor(en) / Beteiligte

• Xu, Shenzhen
• Li, Lesheng
• Carter, Emily A

Titel

Why and How Carbon Dioxide Conversion to Methanol Happens on Functionalized Semiconductor Photoelectrodes

Ist Teil von

• Journal of the American Chemical Society, 2018-12, Vol.140 (48), p.16749-16757

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2018

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Functionalization of semiconductor electrode surfaces with adsorbed 2-pyridinide (2-PyH–*) has been postulated to enable selective CO2 photoelectroreduction to CH3OH. This hypothesis is supported by recent estimates of sufficient 2-PyH–* lifetimes and low barriers for hydride transfer (HT) to CO2. However, the complete mechanism for reducing CO2 to CH3OH remained unidentified. Here, vetted quantum chemistry protocols for modeling GaP reveal a pathway involving HTs to specific CO2 reduction intermediates. Predicted barriers suggest that HT to HCOOH requires adsorbed HCOOH* reacting with 2-PyH–*, a new catalytic role for the surface. HT to HCOOH* produces CH2(OH)2, but subsequent HT to CH2(OH)2 forming CH3OH is hindered. However, CH2O, dehydrated CH2(OH)2, easily reacts with 2-PyH–*, producing CH3OH. Further reduction of CH3OH to CH4 via HT from 2-PyH–* encounters a high barrier, consistent with experiment. Our finding that the GaP surface enables HT to HCOOH* explains why the primary CO2 reduction product over CdTe photoelectrodes is HCOOH rather than methanol, as HCOOH does not adsorb on CdTe and so the reaction terminates. The stability of 2-PyH–* (vs its protonation product DHP*), the relative dominance of CH2(OH)2 over CH2O, and the required desorption of CH2(OH)2* are the most likely limiting factors, explaining the low yield of CH3OH observed experimentally.