Details

Autor(en) / Beteiligte

• Liu, Si-Wei
• Gao, Ying-Juan
• Shi, Yin
• Zhou, Lin
• Tang, Xue
• Cui, Hai-Lei

Titel

Synthesis of Benzoindolizines through 1,5-Electrocyclization/Oxidation Cascades

Ist Teil von

• Journal of organic chemistry, 2018-11, Vol.83 (22), p.13754-13764

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2018

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• This study presents a convenient synthesis of pyrrolo­[1,2-a]­quinolines and pyrrolo­[2,1-a]­isoquinolines with simple quinolines or isoquinolines and Morita–Baylis–Hillman carbonates in the presence of copper acetate. A range of functionalized benzoindolizines could be assembled through an SN2′/deprotonation/1,5-electrocyclization/oxidation cascade pathway in a one-step process.