Details

Autor(en) / Beteiligte

• Holmes, Jessica L
• Abrahams, Brendan F
• Ahveninen, Anna
• Boughton, Berin A
• Hudson, Timothy A
• Robson, Richard
• Thinagaran, Dinaiz

Titel

Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds

Ist Teil von

• Chemical communications (Cambridge, England), 2018-10, Vol.54 (84), p.11877-11880

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2018

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A robust, nano-sized covalent cage, of composition, [(PhSi) (ctc) ] (H ctc = cyclotricatechylene) has been prepared in a simple reaction in good yield. The tetrahedral anionic cage is stable in both the solid and solution state and exhibits an affinity for Cs ions which bind to the internal surface of the cage.