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Enhanced photovoltage for inverted planar heterojunction perovskite solar cells
Ist Teil von
Science (American Association for the Advancement of Science), 2018-06, Vol.360 (6396), p.1442-1446
Ort / Verlag
United States: The American Association for the Advancement of Science
Erscheinungsjahr
2018
Link zum Volltext
Quelle
Science Online_科学在线
Beschreibungen/Notizen
The highest power conversion efficiencies (PCEs) reported for perovskite solar cells (PSCs) with inverted planar structures are still inferior to those of PSCs with regular structures, mainly because of lower open-circuit voltages (
). Here we report a strategy to reduce nonradiative recombination for the inverted devices, based on a simple solution-processed secondary growth technique. This approach produces a wider bandgap top layer and a more n-type perovskite film, which mitigates nonradiative recombination, leading to an increase in
by up to 100 millivolts. We achieved a high
of 1.21 volts without sacrificing photocurrent, corresponding to a voltage deficit of 0.41 volts at a bandgap of 1.62 electron volts. This improvement led to a stabilized power output approaching 21% at the maximum power point.