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•Chitosan film with citric acid cross linker and glycerol plasticizer was prepared.•Its properties were compared with that of neat chitosan film.•It showed better transparency, water resistance and moisture barrier properties.•The mechanical, thermal and antioxidant properties of the film were improved.•The film was used to pack green chillies and found to enhance their shelf life.
Chitosan films with cross linker and plasticizer were prepared using solvent casting method for food packaging application. Citric acid was used as the cross linker which enhances the stability of the films. Glycerol was used as plasticizer which imparts flexibility. Successful cross linking was confirmed by Fourier Transform-Infra Red (FT-IR) spectra and incorporation of glycerol was seen clearly in the Field Emission Scanning Electron Microscope (FE-SEM) images. The modified films show an improved water resistance and transparency. An improved moisture barrier was also observed with a 5.5% and 29% reduction in water vapor transmission and water vapor permeability, respectively. Modified films showed drastic 12 times increase in the elongation percentage value, hence enhanced flexibility. However, the tensile strength and Young’s modulus decreased substantially by 82% and 98%, respectively. The films also showed better thermal and antioxidant properties as compared to neat chitosan films and were found to enhance green chilli shelf life.