Angewandte Chemie (International ed.), 2001-01, Vol.40 (1), p.231-234
2001
Volltextzugriff (PDF)
Details
- Autor(en) / Beteiligte
- Titel
- Asymmetric Total Synthesis of Rhizoxin D
- Ist Teil von
- Angewandte Chemie (International ed.), 2001-01, Vol.40 (1), p.231-234
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag GmbH
- Erscheinungsjahr
- 2001
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Catalytic asymmetric allylation (CAA) using tributyl‐(2‐ethylallyl)stannane as a methyl ethyl ketone equivalent plays a key role in this synthesis of rhizoxin D. A subsequent substrate‐directed acetal aldol reaction, fragment assembly by a modified Julia procedure, and directed electron transfer reduction are used to complete the synthesis (see scheme).
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/1521-3773(20010105)40:1<231::AID-ANIE231>3.0.CO;2-WTitel-ID: cdi_proquest_miscellaneous_2033378709
- Format
- –
- Schlagworte
- allylation, antitumor agents, asymmetric catalysis, samarium, total synthesis