Angewandte Chemie (International ed.), 1999-02, Vol.38 (3), p.351-354
1999
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Details
- Autor(en) / Beteiligte
- Titel
- Continuous Amination of Propanediols in Supercritical Ammonia
- Ist Teil von
- Angewandte Chemie (International ed.), 1999-02, Vol.38 (3), p.351-354
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag GmbH
- Erscheinungsjahr
- 1999
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Enhancements in selectivity by a factor of 4 to 18 were observed in the near critical regions of ammonia during the Co‐ and Ni‐catalyzed synthesis of 1,3‐diaminopropanes. These results are attributed to the higher concentration of ammonia at the surface of the catalyst, which favors the amination and suppresses degredation reactions.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/(SICI)1521-3773(19990201)38:3<351::AID-ANIE351>3.0.CO;2-0Titel-ID: cdi_proquest_miscellaneous_2033376997
- Format
- –
- Schlagworte
- Aminations, Ammonia, Diols, Heterogeneous catalysis, Supercritical fluids