Analytical and bioanalytical chemistry, 2018-02, Vol.410 (6), p.1657-1665
2018
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- Autor(en) / Beteiligte
- Titel
- Magnetic covalent triazine-based frameworks as magnetic solid-phase extraction adsorbents for sensitive determination of perfluorinated compounds in environmental water samples
- Ist Teil von
- Analytical and bioanalytical chemistry, 2018-02, Vol.410 (6), p.1657-1665
- Ort / Verlag
- Berlin/Heidelberg: Springer Berlin Heidelberg
- Erscheinungsjahr
- 2018
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- Covalent organic frameworks (COFs), which are a new type of carbonaceous polymeric material, have attracted great interest because of their large surface area and high chemical and thermal stability. However, to the best of our knowledge, no work has reported the use of magnetic COFs as adsorbents for magnetic solid-phase extraction (MSPE) to enrich and determine environmental pollutants. This work aims to investigate the feasibility of using covalent triazine-based framework (CTF)/Fe 2 O 3 composites as MSPE adsorbents to enrich and analyze perfluorinated compounds (PFCs) at trace levels in water samples. Under the optimal conditions, the method developed exhibited low limits of detection (0.62–1.39 ng·L -1 ), a wide linear range (5–4000 ng L -1 ), good repeatability (1.12–9.71%), and good reproducibility (2.45–7.74%). The new method was successfully used to determine PFCs in actual environmental water samples. MSPE based on CTF/Fe 2 O 3 composites exhibits potential for analysis of PFCs at trace levels in environmental water samples. Graphical abstract Magnetic covalent triazine-based frameworks (CTFs) were used as magnetic solid-phase extraction adsorbents for the sensitive determination of perfluorinated compounds in environmental water samples. PFBA perfluorobutyric acid, PFBS perfluorobutane sulfonate, PFDA perfluorodecanoic acid, PFDoA perfluorododecanoic acid, PFHpA perfluoroheptanoic acid, PFHxA perfluorohexanoic acid, PFHxS perfluorohexane sulfonate, PFNA perfluorononanoic acid, PFOA perfluorooctanoic acid, PFPeA perfluoropentanoic acid, PFUdA Perfluoroundecanoic acid
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1618-2642eISSN: 1618-2650DOI: 10.1007/s00216-017-0845-1Titel-ID: cdi_proquest_miscellaneous_1989577022
- Format
- –
- Schlagworte
- Acids, Adsorbents, Analytical Chemistry, Biochemistry, Characterization and Evaluation of Materials, Chemical properties, Chemistry, Chemistry and Materials Science, Composite materials, Covalence, Extraction (Chemistry), Feasibility studies, Ferric oxide, Food Science, Identification and classification, Laboratory Medicine, Methods, Monitoring/Environmental Analysis, Organic fluorine compounds, Paper in Forefront, Perfluoro compounds, Perfluorodecanoic acid, Perfluorohexane, Perfluorooctanoic acid, Pollutants, Protozoa, Reproducibility, Solid phases, Thermal stability, Trace levels, Triazine, Water analysis, Water sampling