Details

Autor(en) / Beteiligte

• Webb, D J
• Fitchett, C M
• Lein, M
• Fulton, J R

Titel

Carbodiimides as catalysts for the reduction of a cadmium hydride complex

Ist Teil von

• Chemical communications (Cambridge, England), 2018-01, Vol.54 (5), p.460-462

Ort / Verlag

England: Royal Society of Chemistry

Erscheinungsjahr

2018

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A rare terminal cadmium hydride complex [(BDI)CdH] (BDI = [{N(2,6-iPr C H )C(Me)} CH]) has been synthesised from [(BDI)CdCl] and LiEt BH. The hydride can be reduced to the cadmium(i) dimer, [(BDI)CdCd(BDI)] upon treatment with a catalytic amount of diisopropyl- or dicyclohexylcarbodiimide.