Details

Autor(en) / Beteiligte

• Cabeza, Javier A
• García-Álvarez, Pablo
• González-Álvarez, Laura

Titel

Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes

Ist Teil von

• Chemical communications (Cambridge, England), 2017, Vol.53 (74), p.10275-10278

Ort / Verlag

England

Erscheinungsjahr

2017

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Reactions of the mesityl-amidinato-silylene Si( Bu bzam)Mes (1; Bu bzam = N,N'-bis(tert-butyl)benzamidinato; Mes = mesityl) with three different iridium precursors led, at room temperature, to two iridium(iii) and one iridium(v) complexes featuring one (Ir ) or two (Ir ) cyclometallated silylene ligands. The iridium(iii) complexes are active catalyst precursors for H/D exchange and dehydrogenative borylation of arene C-H bonds.