Details

Autor(en) / Beteiligte

• Sekino, Mio
• Furutachi, Hideki
• Tojo, Rina
• Hishi, Ayumi
• Kajikawa, Hanako
• Suzuki, Takatoshi
• Suzuki, Kaito
• Fujinami, Shuhei
• Akine, Shigehisa
• Sakata, Yoko
• Ohta, Takehiro
• Hayami, Shinya
• Suzuki, Masatatsu

Titel

New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex

Ist Teil von

• Chemical communications (Cambridge, England), 2017-08, Vol.53 (63), p.8838-8841

Ort / Verlag

England

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A (μ-peroxo)diiron(iii) complex [Fe (L )(O )(Ph CCO )] (1-O ) with a dinucleating ligand (L ), generated from the reaction of a carboxylate bridged diiron(ii) complex [Fe (L )(Ph CCO )] (1) with dioxygen in CH Cl , provides a diiron(iv)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.