Details

Autor(en) / Beteiligte

• Shimomaki, Katsuya
• Murata, Kei
• Martin, Ruben
• Iwasawa, Nobuharu

Titel

Visible-Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts

Ist Teil von

• Journal of the American Chemical Society, 2017-07, Vol.139 (28), p.9467-9470

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2017

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A highly useful, visible-light-driven carboxylation of aryl bromides and chlorides with CO2 was realized using a combination of Pd­(OAc)2 as a carboxylation catalyst and Ir­(ppy)2­(dtbpy)­(PF6) as a photoredox catalyst. This carboxylation reaction proceeded in high yields under 1 atm of CO2 with a variety of functionalized aryl bromides and chlorides without the necessity of using stoichiometric metallic reductants.