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Wetting behaviour of Cu based alloys on spinel substrates in pyrometallurgical context
Ist Teil von
Materials science and technology, 2015-12, Vol.31 (15), p.1925-1933
Ort / Verlag
London, England: Taylor & Francis
Erscheinungsjahr
2015
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Metal droplet losses in slags are an important issue in copper industry. One significant aspect that promotes the entrainment of metal droplets in the slag is their attachment to spinel solids. In the present study, the wetting behaviour of copper alloys on spinel substrates has been investigated in the presence and absence of a slag phase. At first, the attachment was investigated using a synthetic slag containing spinel particles. Microstructural analysis of quenched slag reveals the presence of microdroplets sticking onto a surface of the spinel particles. Second, the metal-spinel interaction was investigated using the sessile drop technique. Wetting angle measurements were performed between Cu-Ag alloys and MgAl
2
O
4
substrates. A non-wetting behaviour between the alloys and substrates was observed. The results suggest that the oxygen partial pressure and the amount of Ag in the alloy both influence the wetting behaviour.