Details

Autor(en) / Beteiligte

• Qin, Lei
• Yu, You-Zhu
• Liao, Pei-Qin
• Xue, Wei
• Zheng, Zhiping
• Chen, Xiao-Ming
• Zheng, Yan-Zhen

Titel

A "Molecular Water Pipe": A Giant Tubular Cluster {Dy72} Exhibits Fast Proton Transport and Slow Magnetic Relaxation

Ist Teil von

• Advanced materials (Weinheim), 2016-12, Vol.28 (48), p.10772-10779

Ort / Verlag

Germany: Blackwell Publishing Ltd

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A lanthanide cluster, PCC‐72, which is the second largest, with 72 Dy(III) ions assembled into an unprecedented tubular structure, is synthesized. Remarkably, PCC‐72 exhibits superionic proton conductivity (>10−4 S cm−1) under both ambient (with relative humidity RH < 75%) and hot (T > 90 °C, RH = 95%) conditions. Moreover, slow magnetic relaxation is observed, making PCC‐72 the largest Dy(III) cluster that is a single‐molecule magnet.