Details

Autor(en) / Beteiligte

• Coulibali, Siomenan
• Deruer, Elsa
• Godin, Elizabeth
• Canesi, Sylvain

Titel

A Stereoselective Arylative-Cyclopropanation Process

Ist Teil von

• Organic letters, 2017-03, Vol.19 (5), p.1188-1191

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A new stereoselective arylative cyclopropanation process involving treatment of halogenated dienone systems in the presence of a Michael donor containing a nitro-aryl-sulfone has been developed. This transformation enables production of an arylated cyclopropane under mild conditions and occurs via a Michael–Smiles ring closure cascade process, reflecting the concepts of green chemistry and atom economy.