Details

Autor(en) / Beteiligte

• Modak, Atanu
• Mondal, Anirban
• Watile, Rahul
• Mukherjee, Semanti
• Maiti, Debabrata

Titel

Remote meta C-H bond functionalization of 2-phenethylsulphonic acid and 3-phenylpropanoic acid derivatives

Ist Teil von

• Chemical communications (Cambridge, England), 2016-01, Vol.52 (96), p.13916-13919

Ort / Verlag

England

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• This discovery illustrates selective meta C-H bond activation from multiple non-equivalent C-H bonds present in medicinally relevant arylethanesulfonic acid and the 2-arylpropanoic acid moiety using weakly coordinating nitrile as a directing group. Transformation of the meta olefinated compounds to important organic molecules has been demonstrated. Efforts were made to obtain mechanistic detail of the meta C-H bond functionalization reaction.