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Optimising Platinum-Rhodium Thermocouple Wire Composition to Minimise Composition Change Due to Evaporation of Oxides
Ist Teil von
Johnson Matthey Technology Review, 2016-10, Vol.60 (4), p.238-242
Ort / Verlag
Johnson Matthey
Erscheinungsjahr
2016
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Barring the presence of significant amounts of impurities, an important cause of thermoelectric inhomogeneity and therefore calibration drift of platinum-rhodium thermocouples at high temperatures is the vaporisation and transport of the oxides of Pt and Rh, which causes local changes
in wire composition. By examining the vapour pressures of Pt and Rh oxides and their temperature dependence, it is shown that at a given temperature there is an optimal wire composition at which evaporation of the oxides has no effect on the wire composition, provided the vapour does not leave
the vicinity of the wire. This may also have applications for Pt-Rh heater elements.