Angewandte Chemie International Edition, 2017-02, Vol.56 (9), p.2459-2463
International ed. in English, 2017
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Details
- Autor(en) / Beteiligte
- Titel
- Highly Stereoselective Gold‐Catalyzed Coupling of Diazo Reagents and Fluorinated Enol Silyl Ethers to Tetrasubstituted Alkenes
- Ist Teil von
- Angewandte Chemie International Edition, 2017-02, Vol.56 (9), p.2459-2463
- Auflage
- International ed. in English
- Ort / Verlag
- Germany: Wiley Subscription Services, Inc
- Erscheinungsjahr
- 2017
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- We report a highly stereoselective synthesis of all‐carbon or fluorinated tetrasubstituted alkenes from diazo reagents and fluorinated enol silyl ethers, using C−F bond as a synthetic handle. Cationic AuI catalysis plays a key role in this reaction. Remarkable fluorine effects on the reactivity and selectivity was also observed. A golden way to alkenes: A stereoselective synthesis of all‐carbon or fluorinated tetrasubstituted alkenes from diazo reagents and fluorinated enol silyl ethers under cationic gold(I) catalysis was developed. Remarkable fluorine effects on the reactivity and selectivity were observed.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.201611625Titel-ID: cdi_proquest_miscellaneous_1861571908
- Format
- –
- Schlagworte
- Alkenes, Catalysis, coupling reactions, diazo reagents, Ethers, Fluorination, Fluorine, fluorine effects, Gold, gold catalysis, olefination, Reagents, Selectivity