Details

Autor(en) / Beteiligte

• Dyapa, Rajendar
• Dockery, Lance T
• Walczak, Maciej A

Titel

Dehydrative glycosylation with cyclic phosphonium anhydrides

Ist Teil von

• Organic & biomolecular chemistry, 2017, Vol.15 (1), p.51-55

Ort / Verlag

England

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Cyclic phosphonium anhydrides generated from bis-phosphine oxides and trifluoromethanesulfonic anhydride are shown as general coupling reagents in a dehydrative glycosylation reaction of C1-hemiacetals. This reaction protocol is characterized by a broad substrate scope and high yields, including reactions of O-, C-, N-, and S-based nucleophiles with furanose, pyranose, and deoxysugar donors.