Details

Autor(en) / Beteiligte

• Orain, David
• Guillemin, Jean-Claude

Titel

Synthesis of Functionalized Deuterioallylic Compounds

Ist Teil von

• Journal of organic chemistry, 1999-05, Vol.64 (10), p.3563-3566

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

1999

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Functionalized deuterioallylic compounds were efficiently prepared by reaction of the corresponding propargylic derivative with the Schwartz reagent followed by hydrolysis of the adduct with D2O. The Z-3-deuterio-2-propenylstannane, prepared in pure form for the first time, is a useful reagent for the preparation of deuterioallylic compounds which cannot be synthesized by hydrozirconation of the corresponding derivatives.