Details

Autor(en) / Beteiligte

• Zhang, Luyan
• Li, Yanru
• Jin, Long-Yi
• Liang, Fushun

Titel

Metal-free C–N cross-coupling of electrophilic compounds and N-haloimides

Ist Teil von

• RSC advances, 2015-01, Vol.5 (80), p.65600-65603

Erscheinungsjahr

2015

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• When DBU is added, the cross-coupling reaction between alkyl halides (halogen = Cl, Br and I) and N -haloimides (halogen = Cl, Br) occurs, resulting in the formation of aminated products. A halogen bond activated nucleophilic substitution mechanism was proposed. The methodology represents an elegant example of applying the halogen bond activation strategy in an organic transformation.