Details

Autor(en) / Beteiligte

• Sebastiani, Federico
• Wolf, Stefan L. P.
• Born, Benjamin
• Luong, Trung Quan
• Cölfen, Helmut
• Gebauer, Denis
• Havenith, Martina

Titel

Water Dynamics from THz Spectroscopy Reveal the Locus of a Liquid–Liquid Binodal Limit in Aqueous CaCO3 Solutions

Ist Teil von

• Angewandte Chemie (International ed.), 2017-01, Vol.56 (2), p.490-495

Auflage

International ed. in English

Ort / Verlag

Weinheim: Wiley Subscription Services, Inc

Erscheinungsjahr

2017

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Many phenomena depend on CaCO3 nucleation where the role of water remains enigmatic. Changes in THz absorption during the early stages of CaCO3 nucleation evidence altered coupled motions of hydrated calcium and carbonate ions. The direct link between these changes and the continuous development of the ion activity product reveals the locus of a liquid–liquid binodal limit. The data strongly suggest that proto‐structured amorphous CaCO3 forms through solidification of initially liquid precursors. Furthermore, polycarboxylates, which stabilize liquid precursors of CaCO3, significantly enhance the kinetic stability of the metastable liquid–liquid state, but they do not affect the locus of the binodal limit. The importance of water network dynamics in phase separation mechanisms can be understood based on the notions of the pre‐nucleation cluster pathway, and is likely to be more general for aqueous systems. Hard water: To delineate the phase diagram of aqueous calcium carbonate, THz spectroscopy was combined with a titration assay to determine the locus of a liquid–liquid binodal limit, which is crucial for understanding calcium carbonate precipitation pathways. This includes elucidating the role of polyanions in stabilizing so‐called polymer‐induced liquid precursors, which are central to biomineralization.