Details

Autor(en) / Beteiligte

• Guo, Jing-Jing
• Hu, Anhua
• Chen, Yilin
• Sun, Jianfeng
• Tang, Haoming
• Zuo, Zhiwei

Titel

Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex

Ist Teil von

• Angewandte Chemie (International ed.), 2016-12, Vol.55 (49), p.15319-15322

Auflage

International ed. in English

Ort / Verlag

Germany: Blackwell Publishing Ltd

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A general strategy for the cleavage and amination of C−C bonds of cycloalkanols has been achieved through visible‐light‐induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C−C bond cleavage and functionalization of unstrained secondary cycloalkanols. Breaking (D)BAD: A general strategy for the cleavage and amination of C−C bonds of cycloalkanols has been achieved through visible‐light‐induced photoredox catalysis utilizing a cerium(III) chloride complex. This method represents the first example of catalytic C−C bond cleavage and functionalization of unstrained secondary cycloalkanols. DBAD=di‐tert‐butyl azodicarboxylate, Boc=tert‐butoxycarbonyl.