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Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex
Ist Teil von
Angewandte Chemie (International ed.), 2016-12, Vol.55 (49), p.15319-15322
Auflage
International ed. in English
Ort / Verlag
Germany: Blackwell Publishing Ltd
Erscheinungsjahr
2016
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
A general strategy for the cleavage and amination of C−C bonds of cycloalkanols has been achieved through visible‐light‐induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C−C bond cleavage and functionalization of unstrained secondary cycloalkanols.
Breaking (D)BAD: A general strategy for the cleavage and amination of C−C bonds of cycloalkanols has been achieved through visible‐light‐induced photoredox catalysis utilizing a cerium(III) chloride complex. This method represents the first example of catalytic C−C bond cleavage and functionalization of unstrained secondary cycloalkanols. DBAD=di‐tert‐butyl azodicarboxylate, Boc=tert‐butoxycarbonyl.