Details

Autor(en) / Beteiligte

• Elsayed Moussa, M
• Attenberger, B
• Peresypkina, E V
• Fleischmann, M
• Balázs, G
• Scheer, M

Titel

Facile synthesis of one-dimensional organometallic-organic hybrid polymers based on a diphosphorus complex and flexible bipyridyl linkers

Ist Teil von

• Chemical communications (Cambridge, England), 2016-01, Vol.52 (65), p.10004-10007

Ort / Verlag

England

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The selective synthesis of a series of new "ladderlike" one-dimensional organometallic-organic hybrid polymers is shown. The polymers are obtained from the reaction of the diphosphorus ligand complex [Cp2Mo2(CO)4(η(2)-P2)] with the copper salt [Cu(CH3CN)4]BF4 in the presence of flexible organic bipyridyl linkers in high selectivity. This unique behaviour is supported by DFT calculations.