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A quasi solid state dye sensitized solar cell based on gelatin/multiwalled carbon nanotube gel electrolyte and ZnO nanorod photoanode
Ist Teil von
Journal of materials science. Materials in electronics, 2016-08, Vol.27 (8), p.7864-7875
Ort / Verlag
New York: Springer US
Erscheinungsjahr
2016
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
One-dimensional zinc oxide (ZnO) nanostructures have a strong impact on dye sensitized solar cells (DSSCs) as a photoanode. Such a nanostructure offers a direct route to the anode for photo-generated electrons resulting from the increased carrier recombination resistance. This manuscript is concerned with the formation of different aspect ratio ZnO nanorod (8–20) by a simple hydrothermal method and the use of such nanorods into the photoanode. The carboxy-functionalized multiwalled carbon nanotubes (COOH-MWCNT) immobilized into gelatin hydrogel was taken as the gel electrolyte. At an optimum concentration of 0.2 % MWCNT, the fabricated device shows an open circuit voltage (V
oc
) of 0.934 V, short circuit current density (J
sc
) of 8.143 mA/cm
2
and power conversion efficiency (PCE) of 1.35 % for ZnO nanorods with aspect ratio 20. On the other hand, the conventional ZnO shows only V
oc
of 0.743 V, J
sc
of 5.525 mA/cm
2
and PCE of 0.21 % under identical condition. This novel fabrication method can thus be considered as a simple and improved way to well-defined photoanodes for quasi solid state DSSCs.